D. M. Burland, C. A. Walsh, F. Kajzar, and C. Sentein, "Comparison of hyperpolarizabilities obtained with different experimental methods and theoretical techniques," J. Opt. Soc. Am. B 8, 2269-2281 (1991)
Second- and third-order hyperpolarizabilities that are obtained with various experimental and theoretical techniques are compared. This comparison requires care in the conventions used in defining the various parameters that enter the data analysis. Experimental values of γ are obtained for p-dioxane, n-hexane, acetone, CHCl3, CCl4, and benzene with both third-harmonic generation and electric-field-induced second-harmonic generation techniques. In addition, values of γ and β for 2-methyl, 4-nitroaniline in p-dioxane and CHCl3 are reported. These experimental results are compared with values of γ and β obtained from a finite-field semiempirical calculation.
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Ref. 34.
Suprasil fused silica.
Ref. 31.
Ref. 11.
Ref. 35.
Ref. 36.
Values of nω in parentheses are calculated from experimental values of lc and n2ω measured with an Abbe refractometer at 532 nm.
Table 3
Molecular Hyperpolarizabilities γ(−3ω; ω, ω, ω) for MNA
Ref. 40, extrapolated to zero-frequency using a quadratic function of frequency.
Quadratic extrapolation to zero frequency with experimental values measured at 1.064 and 1.907 μm.
Ref. 39.
Ref. 46.
This work.
Tables (7)
Table 1
Parameters Used in Analyzing the Third-Harmonic Experimental Data with Eq. (19)
Ref. 34.
Suprasil fused silica.
Ref. 31.
Ref. 11.
Ref. 35.
Ref. 36.
Values of nω in parentheses are calculated from experimental values of lc and n2ω measured with an Abbe refractometer at 532 nm.
Table 3
Molecular Hyperpolarizabilities γ(−3ω; ω, ω, ω) for MNA
Ref. 40, extrapolated to zero-frequency using a quadratic function of frequency.
Quadratic extrapolation to zero frequency with experimental values measured at 1.064 and 1.907 μm.
Ref. 39.
Ref. 46.
This work.