Precise measurements of hyperfine components in the spectrum of molecular iodine

Craig J. Sansonetti

doi:10.1364/JOSAB.14.001913

Journal of the Optical Society of America B
Vol. 14,
Issue 8,
pp. 1913-1920
(1997)
•https://doi.org/10.1364/JOSAB.14.001913

Precise measurements of hyperfine components in the spectrum of molecular iodine

Craig J. Sansonetti

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Craig J. Sansonetti, "Precise measurements of hyperfine components in the spectrum of molecular iodine," J. Opt. Soc. Am. B 14, 1913-1920 (1997)

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Abstract

Absolute wave numbers with a typical uncertainty of 1 MHz (95% confidence) were measured for 102 hyperfine-structure components of $^{127} I_{2} .$ The data cover the range 560 to 656 nm with no gaps larger than $50 {cm}^{- 1} .$ The spectra were observed by use of Doppler-free frequency-modulation spectroscopy with a tunable cw laser. The laser was locked to selected iodine components, and its wave number was measured with a high-precision Fabry–Perot wavemeter. The accuracy of the results is confirmed by the good agreement of nine of the lines with previous results from other laboratories. These measurements provide a well-distributed set of precise reference lines for this spectral region.

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Atlas Wave Numbera $({cm}^{- 1})$	Transition	Component	Measured Wave Numberb $({cm}^{- 1})$	Commentsc
15 233.3653	$R 73$ (5–5)	$i$	15 233.367441 (24)	21 U $(p, q)$
15 278.5914	$P 110$ (6–5)	$t$	15 278.574318 (25)	15 U $(d, e) (f, g) (p, q)$
15 297.7275	$P 100$ (6–5)	$t$	15 297.712483 (25)	15 U $(d, e) (f, g) (p, q)$
				$P 149$ (7–5) $- 790 MHz$ 15%
15 341.8700	$P 72$ (6–5)	$t$	15 341.853034 (27)	15 U $(d, e) (f, g)$
15 379.2371	$R 41$ (6–5)	$t$	15 379.221566 (25)	21 R
				$R 75$ (10–7) $- 70 MHz$ 3%
15 406.9515	$P 102$ (7–5)	$t$	15 406.937545 (25)	15 U $(d, e) (f, g) (p, q)$
				$R 50$ (10–7) $+ 560 MHz$ 5%
15 411.4059	$R 94$ (5–4)	$t$	15 411.389346 (25)	15 U $(d, e) (f, g) (p, q)$
15 427.3234	$P 77$ (5–4)	$t$	15 427.306474 (25)	21 U $(p, q)$
15 476.0688	$P 55$ (7–5)	$t$	15 476.051750 (27)	21 R
15 524.1299	$P 89$ (6–4)	$t$	15 524.112357 (27)	21 U $(p, q)$
15 575.1479	$R 56$ (6–4)	$t$	15 575.137259 (27)	15 U $(d, e) (f, g)$
15 627.0467	$P 95$ (7–4)	$t$	15 627.030692 (27)	21 U $(p, q)$
15 672.5341	$P 65$ (7–4)	$t$	15 672.517398 (25)	21 R
15 727.5394	$R 22$ (9–5)	$t$	15 727.518573 (24)	15 U $(f, g) (o, p)$
				$P 16$ (9–5) $+ 740 MHz$ 65%
15 758.9686	$R 89$ (8–4)	$t$	15 758.949917 (27)	21 U $(p, q)$
---	$P 33$ (6–3)	$r$	15 797.967821 (27)	21 R
15 807.2941	$R 50$ (8–4)	$t$	15 807.267682 (25)	15 U $(d, e) (f, g)$
				$P 44$ (8–4) $+ 410 MHz$ 70%
				$P 115$ (9–4) $+ 520 MHz$ 25%
				$R 20$ (6–3) $+ 760 MHz$ 10%
15 846.3960	$P 96$ (9–4)	$t$	15 846.384979 (25)	15 U $(d, e) (f, g) (p, q)$
15 856.9424	$R 96$ (9–4)	$t$	15 856.931277 (25)	15 U $(d, e) (f, g) (p, q)$
15 886.5111	$P 61$ (7–3)	$t$	15 886.494949 (25)	21 R
15 919.8992	$R 48$ (9–4)	$t$	15 919.884050 (27)	15 U $(d, e) (f, g)$
15 954.0339	$R 97$ (8–3)	$t$	15 954.016985 (25)	21 U $(p, q)$
				$R 146$ (11–4) $- 160 MHz$ 15%
15 973.6499	$R 91$ (10–4)	$t$	15 973.631183 (25)	21 U $(p, q)$
16 038.2085	$R 36$ (10–4)	$t$	16 038.192673 (25)	15 U $(d, e) (f, g)$
16 052.4447	$R 103$ (9–3)	$t$	16 052.429625 (25)	21 U $(p, q)$
				$R 97$ (7–2) $- 200 MHz$ 10%
16 090.5320	$P 75$ (9–3)	$t$	16 090.515101 (27)	21 R
16 130.0815	$R 47$ (9–3)	$t$	16 130.062709 (27)	21 R
16 172.3266	$P 91$ (10–3)	$t$	16 172.309240 (25)	21 U $(p, q)$
16 205.9611	$R 76$ (10–3)	$t$	16 205.946017 (25)	15 U $(d, e) (f, g) (p, q)$
				$R 78$ (12–4) $- 650 MHz$ 20%
16 254.6514	$P 17$ (10–3)	$t$	16 254.623391 (24)	21 W
				$P 26$ (12–4) $+ 240 MHz$ 20%
16 304.5153	$P 76$ (11–3)	$t$	16 304.499027 (25)	15 U $(d, e) (f, g) (p, q)$
16 339.7841	$R 48$ (9–2)	$t$	16 339.768615 (30)	15 U $(d, e) (f, g)$
16 340.6383	$R 47$ (9–2)	$i$	16 340.658054 (30)	21 R
				$P 48$ (11–3) $- 700 MHz$ 170%
16 341.7580	$P 40$ (9–2)	$t$	16 341.742422 (30)	15 U $(d, e) (f, g) (o, p) (q, r)$
16 394.6975	$P 84$ (10–2)	$t$	16 394.681360 (30)	15 U $(d, e) (f, g) (p, q)$
16 404.6432	$P 78$ (10–2)	$t$	16 404.626597 (25)	15 U $(d, e) (f, g) (p, q)$
16 424.4665	$R 70$ (10–2)	$t$	16 424.450522 (24)	15 U $(d, e) (f, g) (p, q)$
16 452.4119	$R 44$ (10–2)	$t$	16 452.395097 (30)	15 U $(d, e) (f, g)$
				$P 176$ (13–2) $+ 540 MHz$ 5%
16 502.8340	$P 82$ (13–3)	$t$	16 502.817062 (25)	15 U $(d, e) (f, g) (p, q)$
				$P 69$ (17–5) $+ 450$ 7%
16 516.8633	$R 80$ (11–2)	$t$	16 516.846551 (30)	15 U $(d, e) (f, g) (p, q)$
16 568.2732	$P 27$ (11–2)	$t$	16 568.255050 (25)	21 W
				$P 16$ (9–1) $+ 320 MHz$ 4%
16 569.9911	$P 24$ (11–2)	$t$	16 569.974576 (30)	15 U $(d, e) (f, g) (o, p) (q, r)$
16 624.9391	$R 78$ (12–2)	$t$	16 624.923159 (30)	15 U $(d, e) (f, g) (p, q)$
16 638.0457	$R 69$ (12–2)	$i$	16 638.049703 (25)	21 U $(p, q)$
				$P 117$ (13–2) $+ 68 MHz$ 45%
				$R 156$ (14–2) $- 590 MHz$ 20%
16 686.0552	$P 96$ (13–2)	$t$	16 686.039067 (30)	15 U $(d, e) (f, g) (p, q)$
16 745.5928	$R 66$ (13–2)	$t$	16 745.576624 (30)	15 U $(d, e) (f, g)$
16 762.1363	$R 52$ (13–2)	$t$	16 762.120059 (30)	15 U $(d, e) (f, g)$
16 780.8572	$P 26$ (11–1)	$t$	16 780.840058 (24)	15 U $(d, e) (f, g) (o, p) (q, r)$
				$R 169$ (16–2) $+ 730 MHz$ 50%
16 806.6446	$R 95$ (12–1)	$t$	16 806.627895 (25)	21 U $(p, q)$
				$P 187$ (15–1) $+ 620 MHz$ 7%
16 833.1260	$R 80$ (12–1)	$t$	16 833.109663 (30)	15 U $(d, e) (f, g) (p, q)$
16 875.1260	$P 106$ (13–1)	$t$	16 875.109221 (24)	15 U $(d, e) (f, g) (p, q)$
16 891.0383	$P 18$ (12–1)	$t$	16 891.022622 (30)	15 U $(f, g) (o, p)$
16 917.3476	$P 80$ (15–2)	$t$	16 917.332049 (25)	15 U $(d, e) (f, g) (p, q)$
16 951.6035	$R 70$ (13–1)	$t$	16 951.597697 (30)	15 U $(d, e) (f, g) (p, q)$
				$R 105$ (18–3) $- 6805 Mhz$ 1%
17 006.0615	$R 97$ (14–1)	$t$	17 006.044184 (24)	21 U $(p, q)$
17 015.0613	$P 80$ (16–2)	$t$	17 015.045402 (30)	15 U $(d, e) (f, g) (p, q)$
				$P 50$ (20–4) $- 40 MHz$ 10%
				$P 6$ (22–5) $- 1100 MHz$ 2%
17 016.1395	$P 87$ (14–1)	$t$	17 016.122831 (30)	21 U $(p, q)$
17 016.8724	$P 79$ (16–2)	$t$	17 016.856207 (30)	21 U $(p, q)$
17 018.0566	$P 86$ (14–1)	$t$	17 018.039997 (30)	15 U $(d, e) (f, g) (p, q)$
17 018.6605	$P 78$ (16–2)	$t$	17 018.644771 (30)	15 U $(d, e) (f, g) (p, q)$
				$P 90$ (12–0) $- 60 MHz$ 25%
				$P 47$ (20–4) $- 1360 MHz$ 25%
17 021.8254	$P 84$ (14–1)	$t$	17 021.809376 (30)	15 U $(d, e) (f, g) (p, q)$
17 026.8345	$R 78$ (16–2)	$t$	17 026.818913 (30)	15 U $(d, e) (f, g) (p, q)$
17 029.1037	$P 80$ (14–1)	$t$	17 029.088451 (30)	15 U $(d, e) (f, g) (p, q)$
17 030.4320	$P 123$ (15–1)	$t$	17 030.415189 (30)	21 U $(p, q)$
17 038.3948	$P 66$ (16–2)	$t$	17 038.378860 (24)	15 U $(d, e) (f, g) (p, q)$
17 045.9627	$R 122$ (15–1)	$t$	17 045.945455 (25)	15 U $(d, e) (f, g) (p, q)$
				$P 85$ (21–4) $+ 480 MHz$ 15%
17 048.0993	$R 64$ (16–2)	$t$	17 048.083923 (30)	15 U $(d, e) (f, g) (p, q)$
17 049.2328	$P 116$ (15–1)	$t$	17 049.217506 (30)	15 U $(d, e) (f, g) (p, q)$
17 099.3577	$P 86$ (17–2)	$t$	17 099.342383 (30)	15 U $(d, e) (f, g) (p, q)$
17 101.1754	$P 94$ (15–1)	$t$	17 101.180948 (30)	15 U $(d, e) (f, g) (p, q)$
17 123.3262	$P 73$ (17–2)	$t$	17 123.309988 (25)	21 U $(p, q)$
				$P 31$ (21–4) $+ 550 MHz$ 15%
17 144.3553	$R 64$ (17–2)	$t$	17 144.338765 (27)	15 U $(d, e) (f, g) (p, q)$
				$R 83$ (22–4) $- 980 MHz$ 5%
				$P 171$ (18–1) $- 1100 MHz$ 5%
17 157.4114	$R 67$ (15–1)	$t$	17 157.396892 (25)	21 U $(p, q)$
17 166.0191	$P 108$ (16–1)	$t$	17 166.002813 (24)	15 U $(d, e) (f, g) (p, q)$
				$P 67$ (22–4) $+ 90 MHz$ 5%
17 194.9067	$R 30$ (15–1)	$t$	17 194.891763 (30)	15 U $(d, e) (f, g)$
17 199.8446	$R 98$ (16–1)	$t$	17 199.827846 (30)	15 U $(d, e) (f, g) (p, q)$
17 205.8047	$P 98$ (14–0)	$t$	17 205.788933 (25)	15 U $(d, e) (f, g) (p, q)$
				$R 140$ (15–0) $- 60 MHz$ 40%
17 252.0411	$P 74$ (14–0)	$t$	17 252.023212 (30)	15 U $(d, e) (f, g) (p, q)$
				$R 105$ (19–2) $+ 160 MHz$ 50%
17 300.0056	$P 12$ (16–1)	$t$	17 299.991091 (30)	15 R
				$R 168$ (22–2) $- 550 MHz$ 2%
17 349.6773	$R 80$ (15–0)	$t$	17 349.661322 (30)	15 U $(d, e) (f, g) (p, q)$
17 352.2451	$P 62$ (17–1)	$t$	17 352.231328 (22)	15 U $(d, e) (f, g) (p, q)$
17 360.6176	$P 56$ (17–1)	$t$	17 360.601438 (30)	15 U $(d, e) (f, g)$
				$P 149$ (22–2) $- 410 MHz$ 2%
17 380.8317	$P 38$ (17–1)	$t$	17 380.816923 (25)	15 U $(d, e) (f, g)$
17 405.1703	$R 90$ (18–1)	$t$	17 405.154995 (30)	15 U $(d, e) (f, g) (p, q)$ d
17 448.3784	$R 42$ (20–2)	$t$	17 448.363077 (25)	15 U $(d, e) (f, g)$
17 450.7924	$R 78$ (16–0)	$t$	17 450.775435 (30)	15 U $(d, e) (f, g) (p, q)$
17 461.1972	$P 67$ (16–0)	$t$	17 461.182208 (25)	21 U $(p, q)$
17 500.8423	$R 88$ (19–1)	$t$	17 500.827932 (30)	15 U $(d, e) (f, g) (p, q)$
17 501.1370	$R 38$ (16–0)	$t$	17 501.121870 (25)	15 U $(d, e) (f, g)$
				$P 70$ (29–5) $- 500 MHz$ 15%
17 521.7500	$R 77$ (19–1)	$t$	17 521.737626 (25)	21 U $(p, q)$
17 531.3938	$P 67$ (19–1)	$t$	17 531.384093 (25)	21 U $(p, q)$
17 550.0663	$R 76$ (17–0)	$t$	17 550.050483 (30)	15 U $(d, e) (f, g) (p, q)$
				$P 125$ (26–3) $- 350 MHz$ 15%
17 578.5963	$P 26$ (19–1)	$i$	17 578.599454 (26)	15 U $(d, e) (f, g)$
				$R 92$ (25–3) $- 840 MHz$ 30%
17 605.3257	$P 23$ (17–0)	$t$	17 605.308074 (24)	21 W
17 609.8910	$R 18$ (17–0)	$t$	17 609.875064 (30)	15 U $(f, g) (q, r)$
				$P 159$ (23–1)? $+ 430 MHz$ 30%
17 655.9473	$P 42$ (20–1)	$t$	17 655.932802 (30)	15 U $(d, e) (f, g)$
17 668.6723	$R 32$ (20–1)	$t$	17 668.657200 (26)	15 U $(d, e) (f, g)$
17 685.4130	$R 46$ (18–0)	$t$	17 685.398042 (26)	15 U $(d, e) (f, g)$
17 704.6867	$R 19$ (18–0)	$t$	17 704.669058 (26)	21 W
17 742.5173	$P 68$ (19–0)	$t$	17 742.501454 (24)	15 U $(d, e) (f, g) (p, q)$
17 811.1027	$R 84$ (20–0)	$t$	17 811.087494 (27)	15 U $(d, e) (f, g) (p, q)$
				$R 49$ (27–3) $- 100 MHz$ 20%
17 845.2272	$P 28$ (22–1)	$t$	17 845.202199 (27)	15 R
				$R 32$ (22–1) $+ 390 MHz$ 100%

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Tables (1)

Journal of the Optical Society of America B